An unnamed German biathlete has tested positive for a stimulant and Italian bobsleigh athlete William Frullani has also tested positive for a banned substance at the Sochi Winter Olympic Games, according to respective officials on Friday.
A German ski federation official said both of the German athlete's samples tested on Thursday and Friday came back as positive for a stimulant.
"We know who is it but we cannot give a name," the federation's Stefan Schwarzbach said.
"As far as I know it is a stimulant that you sometimes find in extra nutrition."
Earlier, the German Olympic Committee said it had been informed by the International Olympic Committee (IOC) on Thursday evening that a team member had failed a test and a disciplinary commission would convene later in the day after the athlete's B sample was tested.
Frullani, 34,a former track and field athlete, tested positive for the substance dymetylpentylamine, also found in nasal decongestants, and has left the village.
Italian officials said they had got the green light from the IOC to replace Frullani in their four-man bobsleigh team with the competition set for Sunday.
The IOC said before the Olympic Games it was planning to carry out 2,453 tests during the Games, which is a record for a Winter Olympic Games.